PureOs Download 404? (ISO path changed on server)

First you need to install firmware-atheros_20190114-2_all.deb (or firmware-atheros_20190717-2_all.deb) and if this “works” you might edit your sources list and have there (add if needed) something equal to main contrib non-free from debian repository like buster and proceed with # apt update. I hope this helps?